Carbon monoxide, CO

Carbon monoxide has a small linear molecule with a relatively short C-O bond, earlier described as a double bond but nowadays mostly as a triple bond. The valence electrons are slightly drawn towards oxygen, which makes the molecule polar.

Carbon monoxide molecule shown in two ways, from Wikipedia. The C-O triple bond has the unit pm (picometer) which means 10-12 m.

 

CO is an uncolored and non-smelling gas at room temperature. Carbon monoxide is highly toxic since it replaces O2 molecules in hemoglobin, causing suffocation after a short while, and the state continues even after a poisoned person is taken into fresh air. Carbon monoxide is flammable and easily forming CO2 in this reaction: 2CO(g) + O2(g) → 2CO2(g) The gas is found in all types of burning, for example car exhaust gases or smoke from a fire. It is also found in cigarette smoke. Moreover, it has been used in wartime for killing people.

 

 

IR spectrum of carbon monoxide, CO

The IR spectrum of carbon monoxide has a major absorption band at 2100 cm-1 or 4.8 µm, due to unsymmetrical vibration modes.

 

Theoretical IR spectrum of carbon monoxide, CO. The spectrum was simulated at: http://spectralcalc.com/info/about.php.

 

 

The IR spectrum of CO below shows an exhaust gas mixture from an oldtime car without catalytical cleaning. Nowadays, modern car exhaust contains mostly CO2 and H2O - the CO concentration is very low.

IR spectrum of 1942 Packard exhaust, showing a mixture of hydrocarbons, water, carbon monoxide and carbon dioxide. The spectrum was found on Internet in a paper by Jane A. Ganske: http://chemeducator.org/sbibs/s0008006/spapers/860353jg.htm